New constraints on the auriferous Witwatersrand sediment provenance from combined detrital zircon U–Pb and Lu–Hf isotope data for the Eldorado Reef (Central Rand Group,South Africa)     

Nikola Koglin  Armin Zeh  Hartwig E. Frimmel  Axel Gerdes 《Precambrian Research》2010

Combined U–Pb and Lu–Hf isotope analyses of detrital zircon grains from the auriferous Eldorado Reef conglomerate, upper Central Rand Group, reveal new insights into the provenance of the sediments and thus, by implication, possibly also into that of the gold. Most of the detrital zircon grains, which are of magmatic origin, yielded Mesoarchaean ages clustering around 2.94 and 3.06 Ga. A subordinate zircon population gave ages with maxima at 3.28 and 3.44 Ga. The Mesoarchaean zircon grains mostly show super-chondritic ?Hf_t of up to +5.2, whereas the Palaeoarchaean zircon grains have nearly chondritic composition with ?Hf_t between −1.3 and +2.0. The new dataset of the Mesoarchaean zircon populations provides the first unambiguous evidence of the formation of juvenile crust not only at 3.06 but also at 2.94 Ga. As the analysed zircon grains are from the ruditic fraction, they must be derived from a comparatively proximal source in close vicinity to the Central Rand Basin. Based on currently available data, this source was most likely a magmatic arc that existed at the northern edge of the Witwatersrand Block at 3.06 Ga. An additional source might be the 2.94 Ga magmatic rocks of the Kraaipan Greenstone Belt that occurs to the west of the Witwatersrand Block. The minor fraction of Palaeoarchaean zircon grains in the Eldorado Reef perhaps stem from sources that are isotopically similar to the Barberton Greenstone Belt and the Limpopo Belt but were more proximal to the Central Rand Basin.  相似文献   

Simultaneous determination of dissolved organic carbon and total dissolved nitrogen in seawater by high temperature catalytic oxidation: conditions for precise shipboard measurements   总被引：1，自引：0，他引：1  

Xos A. lvarez-Salgado  Axel E. J. Miller 《Marine Chemistry》1998,62(3-4)

Appropriate conditions have been achieved for the accurate, rapid, and highly precise shipboard simultaneous determination of dissolved organic carbon and total dissolved nitrogen in seawater by high temperature catalytic oxidation. A nitrogen-specific Antek 705D chemiluminescence detector and a CO₂-specific LiCor Li6252 IRGA have been coupled in-series with a Shimadzu TOC-5000 organic carbon analyser. Precision of both simultaneous measurements is ≤1.5%, i.e. ±1 μmol C l⁻¹ and ±0.3 μmol N l⁻¹, respectively. Quality of analysis is not compromised by vibrations associated with ocean going research vessels.  相似文献   

Hydrological model parameter (in)stability – “crash testing” the HBV model under contrasting flood seasonality conditions     

Klaus Vormoor  Maik Heistermann  Axel Bronstert  Deborah Lawrence 《水文科学杂志》2018,63(7):991-1007

This paper investigates the transferability of calibrated HBV model parameters under stable and contrasting conditions in terms of flood seasonality and flood generating processes (FGP) in five Norwegian catchments with mixed snowmelt/rainfall regimes. We apply a series of generalized (differential) split-sample tests using a 6-year moving window over (i) the entire runoff observation periods, and (ii) two subsets of runoff observations distinguished by the seasonal occurrence of annual maximum floods during either spring or autumn. The results indicate a general model performance loss due to the transfer of calibrated parameters to independent validation periods of ?5 to ?17%, on average. However, there is no indication that contrasting flood seasonality exacerbates performance losses, which contradicts the assumption that optimized parameter sets for snowmelt-dominated floods (during spring) perform particularly poorly on validation periods with rainfall-dominated floods (during autumn) and vice versa.  相似文献   

Strontium isotope systematics of scheelite and apatite from the Felbertal tungsten deposit,Austria – results of in-situ LA-MC-ICP-MS analysis     

Michael Kozlik  Axel Gerdes  Johann G. Raith 《Mineralogy and Petrology》2016,110(1):11-27

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A low order dynamical model for runoff predictability     

Olson  Roman  Timmermann  Axel  Lee  June-Yi  An  Soon-Il 《Climate Dynamics》2021,56(1-2):399-422

Climate Dynamics - Recent work has identified potential multi-year predictability in soil moisture (Chikamoto et al. in Clim Dyn 45(7–8):2213–2235, 2015). Whether this long-term...  相似文献   

A new U–Pb LA-ICP-MS age of the Rumburk granite (Lausitz Block,Saxo-Thuringian Zone): constraints for a magmatic event in the Upper Cambrian     

Zieger  J.  Linnemann  U.  Hofmann  M.  Gärtner  A.  Marko  L.  Gerdes  A. 《International Journal of Earth Sciences》2018,107(3):933-953

International Journal of Earth Sciences - The basement of the Saxo-Thuringian Zone consists of Upper Neoproterozoic (c. 650-570 Ma) Cadomian arc sediments (Lusatian greywackes) and...  相似文献   

A new U–Pb zircon age and a volcanogenic model for the early Permian Chemnitz Fossil Forest     

Luthardt  Ludwig  Hofmann  Mandy  Linnemann  Ulf  Gerdes  Axel  Marko  Linda  Rößler  Ronny 《International Journal of Earth Sciences》2018,107(7):2465-2489

International Journal of Earth Sciences - The Chemnitz Fossil Forest depicts one of the most completely preserved forest ecosystems in late Paleozoic Northern Hemisphere of tropical Pangaea. Fossil...  相似文献   

The dark side of zircon: textural,age, oxygen isotopic and trace element evidence of fluid saturation in the subvolcanic reservoir of the Island Park-Mount Jackson Rhyolite,Yellowstone (USA)     

Juliana?TrochEmail authorView author&#;s OrcID profile  Ben?S.?Ellis  Axel?K.?Schmitt  Anne-Sophie?Bouvier  Olivier?Bachmann 《Contributions to Mineralogy and Petrology》2018,173(7):54

The Island Park-Mount Jackson series in the Yellowstone volcanic field, Wyoming (USA), is a suite of rhyolitic domes and lavas that erupted between the caldera-forming eruptions of the Mesa Fall Tuff (1.3 Ma) and the Lava Creek Tuff (0.6 Ma). Combined zircon U/Pb geochronology, Raman spectroscopy, oxygen isotopic and trace elemental compositions document storage conditions of these magmas between consecutive supereruptions. Based on comparison with co-erupted melt compositions and textural criteria, four zircon compositional groups are identified that record different stages along a continuous magmatic evolution from trace element-poor rhyolite at high temperatures to extremely fractionated rhyolite where zircon trace elements are highly enriched (e.g., >?1000 ppm U). These latter zircon domains are dark in cathodoluminescence images and show broadened Raman peaks relative to near-endmember zircon, indicating that substitution of non-stoichiometric trace elements into zircon leads to distortion of the crystal lattice. Some of these zircon domains contain inclusions of U-Th-REE-phases, likely originating from coupled dissolution–reprecipitation of metastable trace element-rich zircon in the presence of a fluid phase. Rhyolite-MELTS simulations indicate that at the conditions required to produce the observed enrichment in trace elements, a fluid phase is likely present. These findings illustrate that zircons can be assembled from a variety of co-existing magmatic environments in the same magma reservoir, including near-solidus volatile-rich melts close to the magmatic–hydrothermal transition.  相似文献   

Sr,Nd, and Hf Isotope Composition of Rocks of the Reft Gabbro–Diorite–Tonalite Complex (Eastern Slope of the Middle Urals): Petrological and Geological Implications     

V. N. Smirnov  K. S. Ivanov  Yu. L. Ronkin  P. A. Serov  A. Gerdes 《Geochemistry International》2018,56(6):495-508

This paper reports Rb–Sr and Sm–Nd isotope data on the gabbro–diorite–tonalite rock association of the Reft massif (eastern margin of the Middle Urals) and Lu–Hf isotope data on zircon populations from these rocks. In terms of Nd and Hf isotope composition, the rocks of the studied association are subdivided into two distinctly different groups. The first group consists of gabbros and diorites, as well as plagioclase granites from thin dikes and veins cutting across the gabbros. In terms of ⁴³Nd/¹⁴⁴Nd _i = 0.512518–0.512573 (ε_Nd(T) = +8.6...+9.7) and ¹⁷⁶Hf/¹⁷⁷Hf _i = 0.282961–0.283019 (ε_Hf(T) = +15.9...+17.9), these rocks are practically identical to depleted mantle. Their Nd and Hf model ages show wide variations, but in general are close to their crystallization time. The second group is represented by tonalites and quartz diorites, which compose a large body occupying over half of the massif area. These rocks are characterized by the lower values of ¹⁴³Nd/¹⁴⁴Nd _i = 0.512265–0.512388 (ε_Nd(T) = +3.7...+6.0) and ¹⁷⁶Hf/¹⁷⁷Hf _i = 0.282826–0.282870 (ε_Hf(T) = +11.1...+12.7). The T_DM values of the second group are much (two–three times) higher than their geological age (crystallization time), which indicates sufficiently long crustal residence time of their source. The initial ⁸⁷Sr/⁸⁶Sr in the rocks of both the groups varies from 0.70348 to 0.70495. This is likely explained by the different saturation of melts with fluid enriched in radiogenic Sr. The source of this fluid could be seawater that was buried in a subduction zone with oceanic sediments and released during slab dehydration. Obtained data make it possible to conclude that the formation of the studied gabbro–diorite–tonalite association is a result of spatially and temporally close magma formation processes in the crust and mantle, with insignificant contribution of differentiation of mantle basite magma.  相似文献   

Constraining genesis and geotectonic setting of metavolcanic complexes: a multidisciplinary study of the Devonian Vrbno Group (Hrubý Jeseník Mts., Czech Republic)     

Vojtěch Janoušek  Jaroslav Aichler  Pavel Hanžl  Axel Gerdes  Vojtěch Erban  Vladimír Žáček  Vratislav Pecina  Marta Pudilová  Kristýna Hrdličková  Petr Mixa  Eliška Žáčková 《International Journal of Earth Sciences》2014,103(2):455-483

The low-grade metavolcanic/volcanosedimentary complex of the Devonian Vrbno Group (Silesicum, NE Bohemian Massif, Czech Republic) occurs in two ~NE–SW trending belts, separated by tectonic slices of Cadomian metagranitic paraautochton. (1) The basic–intermediate lavas of the calc-alkaline Western Volcanic Belt came from a moderately depleted mantle $ \left( {\varepsilon_{\text{Nd}}^{370} \sim + 3} \right) $ . Rare rhyolites (374.0 ± 1.7 Ma: 2σ, LA–ICP–MS U–Pb Zrn) were derived most likely from immature crust or by extensive fractionation of primary basaltic melts. The rock association is interpreted as a vestige of a deeply dissected continental arc. (2) The Eastern Volcanic Belt consists mainly of (nearly) contemporaneous (371.0 ± 1.4 Ma) felsic alkaline lavas with high HFSE contents, as well as high Ga/Al and Fe/Mg ratios, typical of within-plate igneous setting. The petrology and Nd–Sr isotopic data point to a high-T anatexis of a young metagranitic crust, resembling the Cadomian (Brunovistulian) basement, in a back-arc setting. The attenuated Brunovistulian lithosphere could have partially melted by the heat provided by the upwelling asthenosphere and/or underplating basic magma. (3) Finally, the region was penetrated by numerous subalkaline, MORB/EMORB-like dolerite sheets—a hallmark of the considerable crustal thinning.  相似文献